Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials     

Weihan Li  Jian‐Ming Zhu  Decan Tan  Guilin Han  Zhouqiao Zhao  Guangliang Wu 《Geostandards and Geoanalytical Research》2020,44(3):523-535

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.  相似文献   

剪切波分裂揭示的青藏高原上地壳地震各向异性基本特征          下载免费PDF全文

郭铁龙  高原 《地球物理学报》2020,63(3):1085-1103

青藏高原整体隆升,构造运动与介质变形强烈,然而由于地震观测数据不足,青藏高原内部上地壳各向异性研究一直是一个空白.本研究使用西藏地区的地震台网(2009年5月—2017年5月)的观测资料,利用剪切波分裂研究青藏高原上地壳地震各向异性特征.由于青藏高原固定地震台站分布稀疏,可用于进行剪切波分裂研究的近场地震事件记录稀少,本研究采用地震事件的单台定位技术,对公开的地震目录里没有震源深度数据的地震事件进行震源位置约束,并引入微震模板匹配定位方法,对连续地震波形进行检索,识别出地震目录里遗漏的新的微震(小地震)事件波形.微震识别获得的新地震事件记录是地震目录里报告的地震事件记录的大约6倍,用于补充研究区的剪切波分裂数据分析.通过数据分析,对比快波偏振方向,证实微震识别获得的数据极大地增加了有效数据的数量,提高了结果的可靠性.研究结果表明,雅鲁藏布江缝合带与班公—怒江缝合带之间的拉萨地块东部地区,台站的快剪切波(快波)偏振方向主要受区域应力场影响,快波偏振方向主要是NS或NNE方向,表明了区域最大主压应力方向;但个别地震台站(当雄台)快波偏振方向受原地主压应力影响,其快波偏振方向既不平行于断裂走向也不平行于区域主压应力方向,揭示出地壳介质的局部变形导致的局部应力方向不同于青藏块体里的其他地区.研究区西部的改则、普兰和研究区北部的双湖,快波偏振方向显示与断裂等构造走向一致的特点.研究区东部的昌都和察隅,快波偏振方向除了与断裂走向(或构造线)一致,还与地表运动的方向相同,揭示了青藏块体东部的深部物质可能的运移方向.这个现象虽然还需更多的研究证实,但这个发现的重要启示是,地震各向异性结合地表变形可用于探讨地壳深部物质的运动.  相似文献   

Dynamic loading tests and seismic response analysis of a stud-type damper composed of multiple friction units with disc springs     

Takeshi Sano  Kazutaka Shirai  Yasumasa Suzui  Yoshikazu Utsumi 《地震工程与结构动力学》2020,49(13):1259-1280

This paper presents an experimental study on the performance of a shear-sliding stud-type damper composed of multiple friction units with high-tension bolts and disc springs. A numerical evaluation of the response reduction effects achieved by the stud-type damper is also presented. In dynamic loading tests, the behavior of stud-type multiunit friction damper specimens was investigated. Three different full-scale damper specimens, which were composed of five, six, or seven friction units with two or four sliding surfaces, were incorporated into loading devices for testing. The stud-type friction dampers demonstrated stable rigid-plastic hysteresis loops without any remarkable decrease in the sliding force even when subjected to repetitive loading, in addition to showing no unstable behavior such as lateral buckling. The damper produced a total sliding force approximately proportional to the number of sliding surfaces and friction units. The total sliding force of the stud-type damper can thus be estimated by summing the contributions of each friction unit. In an earthquake response simulation, the control effects achieved by stud-type dampers incorporated into an analytical high-rise building model under various input waves, including long-period, long-duration and pulse-like ground motions, were evaluated. A satisfactory response reduction was obtained by installing the developed stud-type dampers into the main frame without negatively impacting usability and convenience in terms of building planning.  相似文献   

2019年四川长宁6.0级地震序列时空演化特征及其地震构造环境研究     

宫悦  王宇玺  梁明剑  龙锋  赵敏 《地震》2020,40(4):90-102

地震序列类型能够直观地反映构造应力场环境、 地震构造及孕震环境介质的差异性。 主—余型地震多发生在相对均匀的介质环境, 而前—主—余型地震及震群型地震往往发生在复杂的构造环境。 2019年6月17日四川省宜宾市长宁县发生的6.0级地震余震活动总体呈NW向分布, 其南东段的余震呈相对单一的NW向条带状, 而北西段的余震活动呈现丛集的特征。 两段的地震序列类型也表现出明显的差异性, 南东段地震序列为主—余型, 序列衰减速度较快; 北西段地震序列为震群型, 序列初期衰减非常缓慢, 余震丰富。 此次6.0级地震序列发生在长宁—双河大背斜上, 该复式背斜主要由多个次级褶皱构造和不同走向的伴生断层组成, 结构复杂。 长宁6.0级地震序列的分段性特征表明, 该地震序列不是发生在单一的断裂构造上, 为多个构造级联破裂所导致的复合型地震序列。 此外, 序列北西段余震的深度逐渐变深, 可能预示着该区域受华蓥山断裂带活动的影响, 地震序列对华蓥山断裂带未来地震活动的影响应引起关注。  相似文献   

Analysis of Anomalous Characteristics of Regional Crustal Deformation before the September 16th, 2019 Zhangye MS5.0 Earthquake, Gansu, China     

MA Haiping  WANG Qian  ZHANG Bo  WU Shanyi  WANG Pengtao  DOU Xiying  LI Minjuan 《中国地震研究》2020,34(2):210-218

To study the crustal movement in the vicinity of the epicenter before the Zhangye M_S5.0 earthquake in 2019, the characteristics of crustal deformation before the earthquake are discussed through the GPS velocity field analysis based on the CMONOC data observed from GPS. The baseline time series between two continuous GPS stations and the strain time series of an area among several stations are analyzed in the epicenter area. The resulting time series of baseline azimuth around the epicenter reflects that the energy of the fault in the northern margin of Qilian Mountain is accumulated continuously before 2017. Besides, the movement trend of azimuth slows down after 2017, indicating the stress accumulation on both sides of the seismogenic fault zone has reached a certain degree. The first shear strain and EW-direction linear strain in the epicentral area of the Zhangye M_S5.0 earthquake remain steady after 2017, and the surface strain rate decreases gradually after 2016. It is illustrated that there is an obvious deformation loss at the epicentral region three years before the earthquake, indicating that a certain degree of strain energy is accumulated in this area before the earthquake.  相似文献   

强震下混凝土剪力墙受弯模拟及测试实验研究          下载免费PDF全文

戴勤友  张正瑞 《地震工程学报》2020,42(2):337-344

为提高混凝土剪力墙受弯性能计算的准确度,开展强震下混凝土剪力墙受弯性能试验研究。选取1个混凝土剪力墙对比试件和3个测试试件作为研究对象,对试件施加垂直荷载和水平荷载,模拟强烈地震作用力。试验前期准备工作完成后,建立分离式有限元模型,通过计算混凝土在受压和受拉状态下的损伤弹塑性刚度,完成对有限元模型中混凝土塑性损伤分析,在此基础上,计算混凝土剪力墙受弯承载力。利用有限元模型对3个测试试件进行模拟试验,结果表明,强烈地震后3个试件的荷载-位移曲线均与实际位移值接近,且混凝土剪力墙受弯承载力试验结果与实际值的误差在2%以内,表明试验研究方法具有一定的可行性,数值模拟结果较为准确。  相似文献   

2016年新疆呼图壁6.2级地震前b值异常特征研究   总被引：1，自引：0，他引：1       下载免费PDF全文

刘子璇  冯建刚  王维桐 《地震工程学报》2020,42(1):150-156

利用2009年以来中国地震台网中心地震编目资料,以2016年新疆呼图壁6.2级地震作为研究对象,采用最大似然法进行b值空间扫描计算,获取震前震中及其邻区地震b值的空间图像。研究结果显示,2016年呼图壁6.2级地震发生在震前显著低b值区域,该异常特征可能反映了地震孕育的应力积累过程,印证了b值的物理意义。  相似文献   

基于企业微信的宁波市地震应急工作助手的设计与实现     

张蓓蕾  彭骁  董君磊  李杲  周浩波 《地震地磁观测与研究》2020,41(4):251-263

通过分析市县地震部门的地震应急组织机构、主要职能、关键流程，设计了地震应急工作助手的需求方案。并应用ASP.NET MVC、HTML5等开发技术，基于企业微信，开发了包括震情服务、灾情服务、应急服务、工作报告、资料查询、通知公告、通信录等7大功能的地震应急工作助手软件。该软件具有相对机动灵活、成本低、易于推广使用的优势。多次地震应急演练使用表明，软件能在较大程度上提高地震应急工作的规范化程度和处置效率。  相似文献   

结构震后残余位移研究进展          下载免费PDF全文

刘巴黎  胡进军 《世界地震工程》2020,(3):131-140

结构在强震作用下进入非线性阶段会产生不可恢复的永久位移或残余变形，结构残余位移是震后结构抗震性能和地震损失评估的重要参数，具有重要的理论意义和工程实用价值。为了深入分析残余位移的研究现状，为面向性态抗震设计和抗震韧性评估的地震动强度指标研究提供参考，全面和系统分析了国内外结构残余位移相关文献，介绍了残余位移的定义，重点论述了影响结构残余位移的主要因素，总结归纳了残余位移计算模型、残余位移控制方法及考虑残余位移的抗震性能评估方法，最后讨论了残余位移研究中存在的问题和建议。  相似文献